论文标题
普遍的Rashba电子 - 音波耦合和超导性
Generalized Rashba Electron-Phonon Coupling and Superconductivity in Strontium Titanate
论文作者
论文摘要
SRTIO3以其靠近铁电相的性质而闻名,并显示出具有与量子临界点接近的特征性圆顶行为的超导性的“最佳”兴奋剂。已经提出了几种将这些现象联系起来的机制,但是大量未确定的参数阻止了确定的评估。在这里,我们使用补充了微观模型的Ab tribias计算来研究传导电子之间的线性耦合和在存在自旋轨道耦合的情况下允许使用的铁电软横向模式。我们发现一种强大的Rashba样耦合,对于极地特征向量的特定形式可能会变得令人惊讶。我们表征了对一般特征向量的这种敏感性,以及通过超拉曼散射实验推导的特定形式,我们找到了正确的数量级的BCS配对耦合常数以支持超导性。从头算的计算使我们能够超越线性弹药的常规rashba样相互作用,并自然地解释了圆顶行为,包括特征性的不对称性。该圆顶归因于由于旋转轨道和跳跃能量之间的竞争而导致角动量的动量依赖性淬灭。具有最大TC的最佳密度导致与没有自由参数的实验相当一致。这些结果使广义的Rashba动态耦合与铁电软模式成为一个引人注目的配对机制,以了解掺杂的SRTIO3中的散装超导性。
SrTiO3 is known for its proximity to a ferroelectric phase and for showing an 'optimal' doping for superconductivity with a characteristic dome-like behaviour resembling systems close to a quantum critical point. Several mechanisms have been proposed to link these phenomena, but the abundance of undetermined parameters prevents a definite assessment. Here, we use ab initio computations supplemented with a microscopic model to study the linear coupling between conduction electrons and the ferroelectric soft transverse modes allowed in the presence of spin-orbit coupling. We find a robust Rashba-like coupling, which can become surprisingly strong for particular forms of the polar eigenvector. We characterize this sensitivity for general eigenvectors and, for the particular form deduced by hyper-Raman scattering experiments, we find a BCS pairing coupling constant of the right order of magnitude to support superconductivity. The ab initio computations enable us to go beyond the linear-in-momentum conventional Rashba-like interaction and naturally explain the dome behaviour including a characteristic asymmetry. The dome is attributed to a momentum dependent quenching of the angular momentum due to a competition between spin-orbit and hopping energies. The optimum density for having maximum Tc results in rather good agreement with experiments without free parameters. These results make the generalized Rashba dynamic coupling to the ferroelectric soft mode a compelling pairing mechanism to understand bulk superconductivity in doped SrTiO3.