论文标题

在Europa_s条件下用1和5 keV电子辐射的NaCl - 水冰混合物的VIS光谱:形成颜色中心和NA胶体

VIS spectroscopy of NaCl-water ice mixtures irradiated with 1 and 5 keV electrons under Europa_s conditions: Formation of colour centres and Na colloids

论文作者

Cerubini, Romain, Pommerol, Antoine, Galli, André, Jost, Bernhard, Wurz, Peter, Thomas, Nicolas

论文摘要

最近对欧罗巴的实验室工作和伸缩观察表明,由辐射产生的晶体缺陷引起的黄色氯化钠(NaCl)的相关性。我们通过对不同类型的类似物进行照射(用能量电子)来进一步研究这一过程,其中NaCl以不同的方式与水冰相关。我们产生两种类型的冰冷类似物:紧凑的平板和颗粒颗粒,我们研究了两种粒径(5和70 $μ$ m)。我们在高温温度(100 K)和高真空(10-7 MBAR)条件下进行电子照射,其能量为1和5 keV。我们观察到两种不同类型的颜色中心的形成。在每个样品中形成了所谓的F-中心(460 nm),但是紧凑型平板内的吸收带的强度超过了任何其他冰类似物,并且与纯NaCl晶粒中吸收带的强度相当。到目前为止,在欧罗巴表面尚未检测到M-中心(720 nm),并且在我们对紧凑型平板的照射期间接近检测极限。这些平板可能是Europa_s表面的良好类似物,因为它们主要产生F-Centres。在紧凑的平板和颗粒样品之间已经观察到了其他显着的差异,例如在580 nm处的吸收带归因于Na的胶体,仅在颗粒样品中。此类吸收尚未在先前的研究中报道。

Recent laboratory efforts and telescopic observations of Europa have shown the relevance of a yellow colouration of sodium chloride (NaCl) caused by crystal defects generated by irradiation. We further investigate this process by irradiating (with energetic electrons) different types of analogues where NaCl is associated in different ways to water ice. We produce two types of icy analogues: compact slabs and granular particles where we investigate two particle sizes (5 and 70 $μ$m). We perform electron irradiation at cryogenic temperatures (100 K) and under high vacuum (10-7 mbar) conditions, with energies of 1 and 5 keV. We observe the formation of two different types of colour centres. The so-called F-centres (460 nm) were formed in every sample, but the intensity of the absorption band within the compact slabs surpassed any other icy analogues and was comparable to the intensity of the absorption band within pure NaCl grains. M-centres (720 nm) have not been detected at the surface of Europa so far, and were close to the detection limit during our irradiation of compact slabs. The slabs could be good analogues for Europa_s surface as they produce mainly F-centres. Other notable differences have been observed between compact slabs and granular samples, such as the presence of an absorption band at 580 nm attributed to colloids of Na, exclusively within granular samples. Such absorptions have not been reported in previous studies.

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