论文标题
空心纳米纤维素毫米的推进,变形和限制反应
Propulsion, deformation, and confinement response of hollow nanocellulose millimotors
论文作者
论文摘要
通常使用可能沉积物或被困在狭窄的流动环境中的密集固体颗粒制成微型运动和纳米运动颗粒。如果使用非常低的密度系统以足够的强度携带液体并且仍然会经历推进运动,则应创建更大的电动机。光线,密集的毫米运动也应该能够在收缩中变形更多。毫米是由可渗透的细菌纤维素胶囊产生的,这些纤维素涂有含催化酶的金属有机框架,从而在过氧化水性氢中产生反应性推进。使用粒子跟踪来量化电动机的运动,并使用微毛细血管压缩和通过密闭通道的流动来测量变形。两种不同的推进机制主要取决于运动表面化学:氧气气泡被从亲水毫米体中排出,通过反作用力和浮力驱动运动。疏水毫米状态仍然附着在不断增长的气泡上,并仅通过浮力移动。尽管它们尺寸较大,但低密度胶囊压缩以通过会阻碍并被固体电动机阻塞的收缩。稀疏的结构但相对较大的电动机使它们能够使用最小的固体质量作为运动支撑结构来运输大量液体。
Micromotor and nanomotor particles are typically made using dense solid particles that can sediment or be trapped in confined flow environments. Creation of much larger motors should be possible if a very low-density system is used with sufficient strength to carry liquid and still experience propulsive motion. Light, dense millimotors should also be able to deform more than dense solid ones in constrictions. Millimotors are created from permeable capsules of bacterial cellulose that are coated with catalase-containing metal-organic frameworks, enabling reactive propulsion in aqueous hydrogen peroxide. The motion of the motors is quantified using particle tracking and the deformation is measured using microcapillary compression and flow through confined channels. Two different propulsion mechanisms are dominant depending on the motor surface chemistry: oxygen bubbles are expelled from hydrophilic millimotors, driving motion via reaction force and buoyancy. Hydrophobic millimotors remain attached to growing bubbles and move by buoyancy alone. Despite their large size, the low-density capsules compress to pass through contractions that would impede and be blocked by solid motors. The sparse structure but relatively large size of the motors enables them to transport significant volumes of liquid using minimal solid mass as a motor support structure.