论文标题
在供体桥接系统中的浮标调制下的电子转移
Electron transfer under the Floquet modulation in donor-bridge-acceptor systems
论文作者
论文摘要
电子转移（ET）过程在现代化学中具有广泛的兴趣。随着实验技术的进步，可以通过诸如光结合相互作用来调节ET。在这项工作中，我们研究了在供体桥 - 受体系统中发生的浮子调制下的ET，其速率内核从精确的运动形式主义方程式中投射出来。这与Floquet定理一起使我们能够研究内在的非马克维亚性与驾驶周期性之间的相互作用。观察到的速率内核表现出由桥梁波动引起的Herzberg-Teller样机制，但受到有效调制。
Electron transfer (ET) processes are of broad interest in modern chemistry. With the advancements of experimental techniques, one may modulate the ET via such as the light-matter interactions. In this work, we study the ET under a Floquet modulation occurring in the donor-bridge-acceptor systems, with the rate kernels projected out from the exact disspaton equation of motion formalism. This together with the Floquet theorem enables us to investigate the interplay between the intrinsic non-Markovianity and the driving periodicity. The observed rate kernel exhibits a Herzberg-Teller-like mechanism induced by the bridge fluctuation subject to effective modulation.
