论文标题

通过远程分子相互作用了解布朗但非高斯的扩散

Understanding Brownian yet non-Gaussian diffusion via long-range molecular interactions

论文作者

Chacón, Francisco E. Alban, Rubio, Erick A. Lamilla, Alvarado, Manuel S. Alvarez

论文摘要

在过去的几年中,胶体悬浮液中生物和软物理物理领域的一些实验报告了颗粒位移中的laplacian概率分布(即布朗尼亚语但非高斯扩散)的正常扩散。为了建模这种行为,已经提出了不同的随机模型,所有这些模型都引入了新的随机元素,这些元素包括我们缺乏有关媒体的信息。尽管这些模型在实践中起作用,但由于其本性,对媒体如何与自身相互作用以及布朗尼粒子中的布朗粒子却不超出其目标和范围,这是对媒体如何相互作用的透彻理解。因此,在本文中提出了一个综合数学模型来解释包括分子相互作用在内的布朗但非高斯扩散。基于Gennes和Langevin动力学的界面理论,表明在弱相互作用的流体和零粘度的显微镜状态下的长距离相互作用会导致粒子位移中的拉普拉斯概率分布。此外,结果表明,相变可以解释高扩散率,并导致这种拉普拉斯分布通过在实验中观察到的时间间隔内通过过渡概率进化为高斯。为了验证这些模型预测,Wang等人在磷脂双层上胶体珠的布朗运动的实验数据。使用并将其与理论的结果进行了比较。该比较表明,所提出的模型不仅能够定性地解释布朗尼但非高斯的扩散,而且可以定量地解释。

In the last years, a few experiments in the fields of biological and soft matter physics in colloidal suspensions have reported normal diffusion with a Laplacian probability distribution in the particles displacements (i.e., Brownian yet non Gaussian diffusion). To model this behavior different stochastic models had been proposed, with all of them introducing new random elements that incorporate our lack of information about the media. Although these models work in practice, due to their own nature a thorough understanding of how the media interacts with itself and with the Brownian particle in Brownian yet non Gaussian diffusion is outside of their aim and scope. For this reason, a comprehensive mathematical model to explain Brownian yet non Gaussian diffusion that includes molecular interactions is proposed in this paper. Based on the theory of interfaces by Gennes and Langevin dynamics, it is shown that long-range interactions in a weakly interacting fluid and in a microscopic regime of zero viscosity leads to a Laplacian probability distribution in the particles displacements. Further, it is shown that a phase transition can explain a high diffusivity and causes this Laplacian distribution to evolve towards a Gaussian via a transition probability in the interval of time as it was observed in experiments. To validate these model predictions, the experimental data of the Brownian motion of colloidal beads on phospholipid bilayer by Wang et al. is used and compared with the results of the theory. This comparison suggests that the proposed model not only is able to explain qualitatively the Brownian yet non-Gaussian diffusion, but also quantitatively.

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