论文标题
SMM1:II的益生元分子库存。肽链的基础
The prebiotic molecular inventory of Serpens SMM1: II. The building blocks of peptide chains
论文作者
论文摘要
这项工作旨在通过在中间质量的原始蛇蛇SMM1-A中搜索这组益生元分子来限制星际酰胺的丰富性。 Alma观察是针对Serpens SMM1进行的。将频谱提取到SMM1-A位置,并使用Cassis Line Analysis软件进行分析,以存在许多酰胺和其他分子的特征旋转线。 nh $ _ {2} $ cho,nh $ _ {2} $ cho $ co $ co $ co $ c {12} $ = 1,nh $ _ {2}^{13} $ cho,ch $ _ {3} $ _ {3} $ c(o) ch $ _ {3} $ c(o)ch $ _ {3} $被牢固地检测到,而trans-nhdcho,nh $ _ {2} $ cdo,ch $ _ {3} $ _ {3} $ nhcho $ nhcho $ν$ = 0,1,ch $ _ {3} $ cooh,以及hoch $ cooh,以及hoch $ cooh,以及hoch $ _} $ _ {2}将这项工作的结果与文献中提出的检测进行了比较。一个统一的ch $ _ {3} $ c(o)nh $ _ {2} $/nh $ _ {2} $ cho比率是针对具有巨大物理差异的一组星际源。基于较小的数据样本,可以看到Ch $ _ {3} $ NHCHO的类似比率。 NH $ _ {2} $ CHO的D/H比率约为1--3 \%,接近低质量源IRAS IRAS中的值〜16293--2422B。 Ch $ _ {3} $ C(O)NH $ _ {2} $和NH $ _ {2} $ CHO的形成可能是链接的。在乌云阶段,这些分子在晶粒表面上形成是一种情况。 NH $ _ {2} $ CHO的高d/h比也被视为表明这些分子是在冰的灰尘晶粒上形成的。直接结果,预计酰胺将存在于行星系统形成的最原始材料中,从而提供益生元材料的储层。
This work aims to constrain the abundances of interstellar amides, by searching for this group of prebiotic molecules in the intermediate-mass protostar Serpens SMM1-a. ALMA observations are conducted toward Serpens SMM1. A spectrum is extracted toward the SMM1-a position and analyzed with the CASSIS line analysis software for the presence of characteristic rotational lines of a number of amides and other molecules. NH$_{2}$CHO, NH$_{2}$CHO $ν_{12}$=1, NH$_{2}^{13}$CHO, CH$_{3}$C(O)NH$_{2}$ $ν$=0,1, CH$_{2}$DOH, CH$_{3}$CHO, and CH$_{3}$C(O)CH$_{3}$ are securely detected, while trans-NHDCHO, NH$_{2}$CDO, CH$_{3}$NHCHO $ν$=0,1, CH$_{3}$COOH, and HOCH$_{2}$CHO are tentatively identified. The results of this work are compared with detections presented in the literature. A uniform CH$_{3}$C(O)NH$_{2}$/NH$_{2}$CHO ratio is found for a group of interstellar sources with vast physical differences. A similar ratio is seen for CH$_{3}$NHCHO, based on a smaller data sample. The D/H ratio of NH$_{2}$CHO is about 1--3\% and is close to values found in the low-mass source IRAS~16293--2422B. The formation of CH$_{3}$C(O)NH$_{2}$ and NH$_{2}$CHO is likely linked. Formation of these molecules on grain surfaces during the dark cloud stage is a likely scenario. The high D/H ratio of NH$_{2}$CHO is also seen as an indication that these molecules are formed on icy dust grains. As a direct consequence, amides are expected to be present in the most pristine material from which planetary systems form, thus providing a reservoir of prebiotic material.