论文标题

cuinp2s6跨铁电跃迁的振动特性

Vibrational properties of CuInP2S6 across the ferroelectric transition

论文作者

Neal, Sabine N., Singh, Sobhit, Fang, Xiaochen, Won, Choongjae, Huang, Fei-ting, Cheong, Sang-Wook, Rabe, Karin M., Vanderbilt, David, Musfeldt, Janice L.

论文摘要

为了探索两种共同铁电的特性,我们测量了cuinp2s6在铁电和玻璃跃迁跨的红外和拉曼散射响应,并将我们的发现与对称性分析,相位稳定性的计算以及晶格动力学进行了比较。除了发现铁电过渡温度T_C周围的位移特征和较大的滞后区域外,我们还确定了稳定极相的振动模式,并确认存在两个具有相反极化的铁电变体。在TC下方,TG处的宽松或玻璃状过渡的特征是局部结构的变化,以微妙的峰转移形式和低频率外部CU和内置模式的激活。后者是由于CU/在协调环境中的变化和相关的顺序序列过程所致。此外,TG分为两个步骤,另一个较大的滞后区和重要的潜在散射。结合室温相分离的成像,这项工作为在外部刺激下和超薄极限下研究Cuinp2s6奠定了基础。

In order to explore the properties of a two-sublattice ferroelectric, we measured the infrared and Raman scattering response of CuInP2S6 across the ferroelectric and glassy transitions and compared our findings to a symmetry analysis, calculations of phase stability, and lattice dynamics. In addition to uncovering displacive character and a large hysteresis region surrounding the ferroelectric transition temperature T_C, we identify the vibrational modes that stabilize the polar phase and confirm the presence of two ferroelectric variants with opposite polarizations. Below TC, a poorly understood relaxational or glassy transition at Tg is characterized by local structure changes in the form of subtle peak shifting and activation of low frequency out-of-plane Cu- and In-containing modes. The latter are due to changes in the Cu/In coordination environments and associated order-disorder processes. Moreover, Tg takes place in two steps with another large hysteresis region and significant underlying scattering. Combined with imaging of the room temperature phase separation, this effort lays the groundwork for studying CuInP2S6 under external stimuli and in the ultra-thin limit.

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