论文标题
用CSPBBR $ _3 $微晶直接生长在电极上,检测超低臭氧和氢浓度
Detecting ultra-low ozone and hydrogen concentrations with CsPbBr$_3$ microcrystals direct grown on electrodes
论文作者
论文摘要
高度稳定的臭氧和氢感测元素是根据结晶圆形的立方体CSPBBR $ _3 $ sibsicron Crystals制造的,该晶体由在环境条件下执行的便捷溶液过程合成。结果表明,与先前报道的金属卤化物和基于氧化物的金属相比,此类元素表现出增强的室温气体传感能力。对这些传感组件进行的电测量结果表明,对超低臭氧和氢浓度的反应高,即分别为4 ppb和5 ppm,即使在环境条件下存储了几个月后,感应行为的令人印象深刻的重复性也令人印象深刻。臭氧和氢检测传感器都是自供电的,即它们不需要使用紫外线或加热外部刺激,并且表现出快速检测和短恢复时间。这些有吸引力的特性以及简单的合成条件可以为实现未来的气体传感设备提供简单,高效和低成本的潜在技术。
Highly stable ozone and hydrogen sensing elements were fabricated based on well-crystalline rounded cube-shaped CsPbBr$_3$ submicron crystals, synthesized by a facile solution process performed under ambient conditions. It is shown that such elements demonstrate enhanced room temperature gas sensing ability compared to the previously reported metal halide and oxide-based ones. Electrical measurements performed on these sensing components revealed high response to ultra-low ozone and hydrogen concentrations, namely 4 ppb and 5 ppm respectively, as well as an impressive repeatability of the sensing behavior even after a few months of storage in ambient conditions. Both ozone and hydrogen detecting sensors were self-powered, i.e. they do not require the use of UV or heating external stimuli, and exhibited fast detection and short restoration times. These attractive properties along with the simple synthesis conditions could provide an easy, efficient and low-cost potential technology for the realization of future gas sensing devices.