论文标题
手性分子强场电离中的强差异光电二色性
Strong Differential Photoion Circular Dichroism in Strong-Field Ionization of Chiral Molecules
论文作者
论文摘要
我们研究了强场状态中手性分子的差异电离概率，这是入射光螺旋的函数。为此，我们分析了溴氯氟甲烷（CHBRCLF）的四倍电离，随后碎片分解为四个带电的片段和不同离子化甲基氧雷亚的不同解离通道。我们观察到差异电离概率的变化范围数百分之几。因此，我们得出的结论是，光的螺旋性是指手性分子强场电离速率的理论描述。
We investigate the differential ionization probability of chiral molecules in the strong field regime as a function of the helicity of the incident light. To this end, we analyze the fourfold ionization of bromochlorofluoromethane (CHBrClF) with subsequent fragmentation into four charged fragments and different dissociation channels of the singly ionized methyloxirane. We observe a variation of the differential ionization probability in a range of several percent. Accordingly, we conclude that the helicity of light is a quantity that should be considered for the theoretical description of the strong field ionization rate of chiral molecules.
