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In this paper, we investigate the transmission probabilities in three cases (depending only on the legitimate receiver, depending only the eavesdropper, and depending on both legitimate receiver and eavesdropper) in quantum key distribution (QKD) systems over free-space optical links. To be more realistic, we consider a generalized pointing error scenario, where the azimuth and elevation pointing error angles caused by stochastic jitters and vibrations in the legitimate receiver platform are independently distributed according to a non-identical normal distribution. Taking these assumptions into account, we derive approximate expressions of transmission probabilities by using the Gaussian quadrature method. To simplify the expressions and get some physical insights, some asymptotic analysis on the transmission probabilities is presented based on asymptotic expression for the generalized Marcum Q-function when the telescope gain at the legitimate receiver approaches to infinity. Moreover, from the asymptotic expression for the generalized Marcum Q-function, the asymptotic outage probability over Beckmann fading channels (a general channel model including Rayleigh, Rice, and Hoyt fading channels) can be also easily derived when the average signal-to-noise ratio is sufficiently large, which shows the diversity order and array gain.