论文标题
具有独特1D子带传输特性的硅上的无催化剂纳米线
Ultrathin catalyst-free InAs nanowires on silicon with distinct 1D sub-band transport properties
论文作者
论文摘要
具有一维(1D)子频段结构的超薄INAS纳米线(NW)是高级量子电子设备的有前途的材料,其中低于30 nm的直径限制的尺寸以及SI的CMOS集成方案是非常需要的。在这里,我们演示了两种位点选择性合成方法,它们在Si上实现了外延,高宽高比INWS,超薄直径低于20 nm。第一种方法利用了直接的蒸气 - 固体生长,以通过互换间距,掩盖开口尺寸和增长时间来调整NW直径。第二个方案探讨了独特的反反应生长,通过该增长,INAS NW的侧壁在受控的砷通量和退火时间下被热分解。发现了有趣的动力学依赖性在间隙间距和变薄动力学之间的依赖性,对于稀疏的NW阵列的直径低至12 nm。我们清楚地通过使用后门控的NW领域效应晶体管在低温传输测量中明显的电导步骤来清楚地验证超大NWS中的1D子频段结构。相关模拟显示单次和双变性电导步骤,突出了旋转六边形对称性,并在扩散的1D传输极限中重现实验迹线。在现实的后门配置下进行建模进一步证明了导致不对称的载体分布和脱落性依赖性的脱落的状态。
Ultrathin InAs nanowires (NW) with one-dimensional (1D) sub-band structure are promising materials for advanced quantum-electronic devices, where dimensions in the sub-30 nm diameter limit together with post-CMOS integration scenarios on Si are much desired. Here, we demonstrate two site-selective synthesis methods that achieve epitaxial, high aspect ratio InAs NWs on Si with ultrathin diameters below 20 nm. The first approach exploits direct vapor-solid growth to tune the NW diameter by interwire spacing, mask opening size and growth time. The second scheme explores a unique reverse-reaction growth by which the sidewalls of InAs NWs are thermally decomposed under controlled arsenic flux and annealing time. Interesting kinetically limited dependencies between interwire spacing and thinning dynamics are found, yielding diameters as low as 12 nm for sparse NW arrays. We clearly verify the 1D sub-band structure in ultrathin NWs by pronounced conductance steps in low-temperature transport measurements using back-gated NW-field effect transistors. Correlated simulations reveal single- and double degenerate conductance steps, which highlight the rotational hexagonal symmetry and reproduce the experimental traces in the diffusive 1D transport limit. Modelling under the realistic back-gate configuration further evidences regimes that lead to asymmetric carrier distribution and lifts of the degeneracy in dependence of gate bias.