论文标题
脱钩水分裂：从基础科学到应用
Decoupled Water Splitting: From Basic Science to Application
论文作者
论文摘要
在这篇综述中，我们讨论了破坏性的脱钩水分分裂方案，其中在传统电解中同时产生的氢和氧彼此之间相互接近，将由时间分离的氢和氧气产生步骤取代。我们介绍了主要的解耦策略，包括电解和电化学化学水分裂解周期，以及通过介导氢与氧气进化反应之间的离子交换来促进它们的氧化还原材料。脱钩的水分裂提供了提高的灵活性和鲁棒性，并为可再生能源提供了新的氢生产机会。
In this review, we discuss disruptive decoupled water splitting schemes, in which the concurrent production of hydrogen and oxygen in close proximity to each other in conventional electrolysis is replaced by time- or space-separated hydrogen and oxygen production steps. We present the main decoupling strategies, including electrolytic and electrochemical chemical water splitting cycles, and the redox materials that facilitate them by mediating the ion exchange between the hydrogen and oxygen evolution reactions. Decoupled water splitting offers increased flexibility and robustness and provides new opportunities for hydrogen production from renewable sources.
