论文标题

由包含石墨烯相关材料的预训练制成的多尺度CFRP层压板的工业制造和表征

Industrial manufacturing and characterization of multiscale CFRP laminates made from prepregs containing graphene-related materials

论文作者

Rodriguez-Garcia, Veronica, Gomez, Julio, Cristiano, Francesco, Gude, Maria R.

论文摘要

事实证明,在碳纤维增强聚合物(CFRP)中引入了与石墨烯相关的材料(GRM),可以增强其机械性和电性能。但是,仍缺乏以工业规模和有效方式生产3阶段材料(多尺度复合材料)的方法。在本文中,已按照航空航天行业目前使用的标准程序制造了包含不同GRM的多尺度CFRP复合材料,目的是评估其潜在应用。石墨纳米细胞骨架(GNP),原位去角质石墨烯(GO)和氧化石墨烯还原(RGO)已分散到环氧树脂树脂中,以便随后浸渍了航空级的碳纤维纤维胶带。所得的预处理已用于在180°C下用手工上篮和高压釜固化制造层压板。已经开展了国外表征运动,以了解不同的多尺度层压板的行为。通过热演化技术评估了治愈程度,玻璃过渡温度和降解温度的程度。同样,它们的机械性能(拉伸,弯曲,平面剪切,层间剪切和模式I I Interlaminar骨折韧性)与它们的电导率一起进行了分析。产生的制造过程用于生产三相层压板,其质量与常规CFRP一样好。 Goand Rgo的添加导致平面内剪切特性和分层抗性增强,同时添加了GNEMPIMPIMPIMPIMPIMPIMPIMPIMPIMPAIMS。

The introduction of graphene-related materials (GRMs) in carbon fibre-reinforced polymers (CFRP) has been proved to enhance their mechanical and electrical properties. However, methodologies to produce the 3-phase materials (multiscale composites) at an industrial scale and in an efficient manner are still lacking. In this paper, multiscale CFRP composites containing different GRMs have been manufactured following standard procedures currently used in the aerospace industry with the aim to evaluate its potential application. Graphite nanoplateletelets (GNPs), in situ exfoliated graphene oxide (GO) and reduced graphene oxide (rGO) have been dispersed into an epoxy resin to subsequently impregnate aeronautical grade carbon fibre tape. The resulting prepregs have been used for manufacturing laminates by hand lay-up and autoclave curing at 180 °C. Abroad characterization campaign has been carried out to understand the behaviour of the different multiscale laminates manufactured. The degree of cure, glass transition temperature and degradation temperature have been evaluated by thermal evolution techniques. Similarly, their mechanical properties (tensile, flexural, in-plane shear, interlaminar shear and mode I interlaminar fracture toughness) have been analysed together with their electrical conductivity. The manufacturing process resulted appropriated for producing three-phase laminates and their quality was as good as in conventional CFRPs. The addition ofGOand rGO resulted in an enhancement of the in-plane shear properties and delamination resistance while the addition ofGNPimproved the electrical conductivity.

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