论文标题

2H-NBSE2的正常和电荷密度波相中的超快动力学

Ultrafast dynamics in normal and Charge Density Wave phase of 2H-NbSe2

论文作者

Anikin, A., Schaller, R. D., Wiederrecht, G. P., Margine, E. R., Mazin, I. I., Karapetrov, G.

论文摘要

我们使用时间分辨的光泵探针光谱法研究了2H-NBSE $ _2 $中的载体和集体模式动力学,并将结果与​​第一原则计算进行比较。在覆盖正常,电荷密度波(CDW)和超导阶段的宽温度间隔中,对2H-NBSE $ _2 $的宽带超快反射率研究。在瞬态反射率实验中观察到的光谱特征与从带结构计算获得的特定光学转变相关。相干声子的置换激发显示了整个光谱范围内软声声子模式的CDW相关的相干振荡。在低兴奋的线性状态下,此相干声子模式的温度演变显示了该模式的软化到CDW过渡温度t $ _ {CDW} $,随后的硬化在T $ _ {CDW} $以下。宽带探针数据的全局拟合揭示了与特征电子电子,电子音波和声子 - 声子松弛过程相关的四个不同的放松时间。从电子 - 音波耦合的第一个原理计算中,我们将少量的picsecond electron-phonon弛豫时间$τ_2$与特定的声子相关联,频率约为20 meV。另一方面,$τ_3$ 〜100 ps的异常长放松时间与Anharmonicity驱动的声子散射有关。所有弛豫过程都是由二阶CDW相变的异常引起的,这些异常反映在特征松弛时间的温度依赖性和光密度的振幅中。在最高的通电状态下,我们观察到CDW的电子熔化,并在T $ _ {CDW} $下方的模式硬化的消失。

We investigate carrier and collective mode dynamics in 2H-NbSe$_2$ using time-resolved optical pump-probe spectroscopy and compare the results with first-principle calculations. Broadband ultrafast reflectivity studies of 2H-NbSe$_2$ in a wide temperature interval covering the normal, charge density wave (CDW) and superconducting phase were performed. Spectral features observed in the transient reflectivity experiment were associated with specific optical transitions obtained from band structure calculations. Displacive excitation of coherent phonons showed CDW-associated coherent oscillations of the soft phonon mode across the whole spectral range. Temperature evolution of this coherent phonon mode in the low-excitation linear regime shows softening of the mode down to the CDW transition temperature T$_{CDW}$ with subsequent hardening below T$_{CDW}$. The global fit of the broadband probe data reveals four different relaxation times associated with characteristic electron-electron, electron-phonon and phonon-phonon relaxation processes. From first principle calculations of electron-phonon coupling we associate the few picosecond electron-phonon relaxation time $τ_2$ with a specific group of phonons with frequencies around 20 meV. On the other hand, the anomalously long relaxation time of $τ_3$~100 ps is associated with anharmonicity-driven phonon-phonon scattering. All relaxation processes result from anomalies near the second order CDW phase transition that are reflected in the temperature dependencies of the characteristic relaxation times and amplitudes of optical densities. At highest fluences we observe electronic melting of the CDW and disappearance of the mode hardening below T$_{CDW}$.

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