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We experimentally emulate interaction induced blockade and local spin freezing in two and three qubit Nuclear Magnetic Resonance (NMR) architecture. These phenomena are identical to the Rydberg blockade and Rydberg biased freezing. In Rydberg blockade, the simultaneous excitation of two or more atoms is blocked due to the level shift induced by the strong Van der Waal's interaction. In such a strong interaction regime, one can also observe Rydberg biased freezing, wherein the dynamics is confined to a subspace, with the help of multiple drives with unequal amplitudes. Here we drive NMR qubits with specific transition-selective radio waves, while intermittently characterizing the quantum states via quantum state tomography. This not only allows us to track the population dynamics, but also helps to probe quantum correlations, by means of quantum discord, evolving under blockade and freezing phenomena. While, our work constitutes the first experimental simulations of these phenomena in the NMR platform, it is also the first experimental demonstration of Rydberg biased freezing. Moreover, these studies open up interesting quantum control perspectives in exploiting the above phenomena for entanglement generation as well as subspace manipulations.