论文标题

通过时反转对称的螺旋连接的旋转选择性

Spin selectivity through time-reversal symmetric helical junctions

论文作者

Utsumi, Yasuhiro, Entin-Wohlman, Ora, Aharony, Amnon

论文摘要

分析了分析两种轨道通道并连接到两个导线的分子的时间反转对称电荷和自旋转运。证明当自旋流动过程伴随着轨道通道的翻转时,自旋分辨电流是生成的。这个令人惊讶的发现并不矛盾巴达森的定理[J. H. Bardarson,J。Phys。答:数学。理论。 41,405203(2008)]对于两末端连接:Thransprions确实具有两对双层特征值。对于两末端手性分子连接的旋转过滤效果被明确证明,该连接由具有原子内旋转轨道相互作用(SOI)建模的两轨道紧密结合链建模。在通过DNA等有机分子传输的背景下,该作用称为“手性诱导的自旋选择性”(CISS)。该模型表现出自旋切割而不打破时间反转对称性:原子内SOI会引起伴随的自旋和轨道翻转。从无限分子中Bloch状态的角度检查这些过渡,这表明它们会导致Bloch波数的变化,即相互单向的大小,其方向取决于螺旋的左侧和右手。结果,旋转和向下的状态朝相反的方向传播,从而导致CISS效应。为了进一步证实我们的图片,我们为8 $ \ tims $ 8的散射矩阵提供了可分析的表达式。

Time-reversal symmetric charge and spin transport through a molecule comprising two-orbital channels and connected to two leads is analyzed. It is demonstrated that spin-resolved currents are generated when spin-flip processes are accompanied by a flip of the orbital channels. This surprising finding does not contradict Bardarson's theorem [J. H. Bardarson, J. Phys. A: Math. Theor. 41, 405203 (2008)] for two-terminal junctions: the transmission does possess two pairs of doubly-degenerate eigenvalues as required by the theorem. The spin-filtering effect is explicitly demonstrated for a two-terminal chiral molecular junction, modeled by a two-orbital tight-binding chain with intra-atomic spin-orbit interactions (SOI). In the context of transport through organic molecules like DNA, this effect is termed "chirality-induced spin selectivity" (CISS). The model exhibits spin-splitting without breaking time-reversal symmetry: the intra-atomic SOI induces concomitant spin and orbital flips. Examining these transitions from the point of view of the Bloch states in an infinite molecule, it is shown that they cause shifts in the Bloch wave numbers, of the size of the reciprocal single turn, whose directions depend on the left-and right-handedness of the helix. As a result, spin-up and spin-down states propagate in the opposite directions, leading to the CISS effect. To further substantiate our picture, we present an analytically-tractable expression for the 8$\times$8 scattering matrix of such a (single) molecule.

扫码加入交流群

加入微信交流群

微信交流群二维码

扫码加入学术交流群,获取更多资源