论文标题

固定表面纳米泡的稳定性反对扩展:理论和模拟的见解

Stability of Pinned Surface Nanobubbles Against Expansion: Insights from Theory and Simulation

论文作者

Liu, Yawei, Bernardi, Stefano, Widmer-Cooper, Asaph

论文摘要

尽管近年来已经广泛研究了表面纳米泡的生长和溶解,但在压力变化或温度升高下的稳定性尚未受到相同水平的审查。在这里,我们基于经典理论提出了理论预测的压力和温度阈值($ p_c $和$ t_c $),在水中,空气纳米泡的情况下发生了不稳定的生长。我们表明,与未施用和散装气泡相似的气泡$ p_c $和更高的$ t_c $的气泡的大小相似,这表明固定气泡可以承受更大的拉伸应力(负压)和更高的温度。从多体耗散粒子动力学(MDPD)的$ p_c $和$ t_c $的$ p_c $(QASI-TWO二维(Quasi-2D)表面纳米泡)中获得的值与理论预测一致,前提是将增长过程中的横向扩展考虑在内。这表明经过修改的经典热力学描述对于固定的气泡与几种纳米一样小。尽管我们的理论结果和以前的实验之间仍然存在一些差异,但在可以全面了解表面纳米泡的稳定性之前,需要进一步的实验数据。

While growth and dissolution of surface nanobubbles has been widely studied in recent years, their stability under pressure changes or a temperature increase has not received the same level of scrutiny. Here, we present theoretical predictions based on classical theory for pressure and temperature thresholds ($p_c$ and $T_c$) at which unstable growth occurs for the case of air nanobubbles on a solid surface in water. We show that bubbles subjected to pinning have much lower $p_c$ and higher $T_c$ compared to both unpinned and bulk bubbles of similar size, indicating that pinned bubbles can withstand a larger tensile stress (negative pressure) and higher temperatures. The values of $p_c$ and $T_c$ obtained from many-body dissipative particle dynamics (MDPD) simulations of quasi-two-dimensional (quasi-2D) surface nanobubbles are consistent with the theoretical predictions, provided that the lateral expansion during growth is taken into account. This suggests that the modified classical thermodynamic description is valid for pinned bubbles as small as several nanometers. While some discrepancies still exist between our theoretical results and previous experiments, further experimental data is needed before a comprehensive understanding of the stability of surface nanobubbles can be achieved.

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