论文标题

各向异性圆形光钙化硫化物硫化物纳米片

Anisotropic circular photogalvanic effect in colloidal tin sulfide nanosheets

论文作者

Moayed, Mohammad Mehdi Ramin, Li, Fu, Beck, Philip, Schober, Jan-Christian, Klinke, Christian

论文摘要

锡硫化物有望具有非常有趣的特性,例如高光吸收系数和小带隙,而与其他金属辣椒剂相比,毒性较小。然而,锡硫化物生长的原子薄结构的局限性阻碍了这些特性的实验实现。由于胶体合成的柔韧性,可以非常薄,同时且大纳米片合成。电运输测量表明,这些纳米片可以充当较高/OFF/OFF比率和P型行为的现场效应晶体管。电荷传输的温度依赖性表明,晶体中的缺陷是导致孔形成多数载体的原因。在用圆极化的光照明期间,这些晶体在零伏偏置处产生依赖性的光电流,因为它们的对称性被非对称界面(基板和真空吸尘器)打破。此外,观察到的圆形光钙化效应显示出明显的面内各向异性,沿扶手椅方向具有较高的光电流,源自该方向上较高的吸收系数。我们的新见解表明,硫化锡对电子和光电子技术的新功能的潜力,例如作为极化传感器。

Tin sulfide promises very interesting properties such as a high optical absorption coefficient and a small band gap, while being less toxic compared to other metal chalcogenides. However, the limitations in growing atomically thin structures of tin sulfide hinder the experimental realization of these properties. Due to the flexibility of the colloidal synthesis, it is possible to synthesize very thin and at the same time large nanosheets. Electrical transport measurements show that these nanosheets can function as field-effect transistors with high on/off ratio and p-type behavior. The temperature dependency of the charge transport reveals that defects in the crystal are responsible for the formation of holes as majority carriers. During illumination with circularly polarized light, these crystals generate a helicity dependent photocurrent at zero-volt bias, since their symmetry is broken by asymmetric interfaces (substrate and vacuum). Further, the observed circular photogalvanic effect shows a pronounced in-plane anisotropy, with a higher photocurrent along the armchair direction, originating from the higher absorption coefficient in this direction. Our new insights show the potential of tin sulfide for new functionalities in electronics and optoelectronics, for instance as polarization sensors.

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